Interaction of the Fe, Cr, and Mo atoms with oxygen-containing molecules NO, N2O, CO2, NO2, AND SO2
The results of experimental studies of the reaction of atoms of three transition metals with various oxygen-containing oxidizers, NO, N2O, CO2, NO2 и SO2, are presented. The rate constants for these reactions are measured, many for the first time. The results obtained are in close agreement with the published low-temperature measurements. it was demonstrated that the spin-forbidden reactions have an additional activation barrier. At the same time, increases in the heat of reaction and electronegativity of the oxidizer facilitate the occurrence of reactions of this type. In passing from 3d to 4d shells (from Cr to Mo) the reactivity of the atom increases.
Представлены результаты экспериментального исследования реакций атомов трех переходных металлов, Fe, Cr и Mo, с различными кислородосодержащими окислителями: NO, N2O, CO2, NO2 и SO2 Измерены константы скорости этих реакций – многие впервые. Результаты находятся в хорошем согласии с измерениями при низких температурах. Показано, что запрет по спину приводит к дополнительному увеличению высоты активационного барьера, в то время как увеличение теплоты реакции и электроотрицательности окислителя способствуют протеканию данного типа реакций. При переходе от 3d оболочки к 4d оболочке (от Cr к Mo), реакционная способность атома увеличивается.
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