A computational electron-radiation-collision (eRC) model of physicochemical processes and radiation processes in strong shock waves in air at velocities of about 10 km/s is pre-sented. The author's calculation model of the rates of electronic excitation of diatomic molecules in collisions with electrons and the lifetimes of excited states, based on the use of ab-initio data for the Einstein coefficients, is used. The electron temperature is predict-ed by solving the electron energy conservation equation. The calculated data are compared with experimental data for a shock wave in air at a speed of 10.8 km/s.
shock waves at velocities of about 10 km/s, nonequilibrium radiation of strong shock waves, relaxation physicochemical kinetics behind the front of strong shock waves, radia-tive-collision models, experimental data on nonequilibrium radiation, models of excitation of electronic states of diatomic molecules upon collision with electrons.
Применение квазистационарных eRC-моделей для расчета неравновесного излучения
ударных волн при скорости порядка 10 км/с
Представлена расчетная электронно-радиационно-столкновительная (eRC) модель физи¬ко-химических процессов и радиационных процессов в сильных ударных вол-нах в воздухе при скоростях порядка 10 км/с. Используется авторская расчетная мо-дель скоростей электронного возбуждения двухатомных молекул при столкновениях с электронами и времен жизни возбужденных состояний, основанная на использова-нии ab-initio данных для коэффициентов Эйнштейна. Электронная температура предсказывается путем решения уравнения сохранения энергии электронов. Расчет-ные данные сравниваются с экспериментальными данными для ударной волны в воз-духе при скорости 10.8 км/с.
ударные волны при скоростях порядка 10 км/с, неравновесное излучение сильных ударных волн, релаксационная физико-химическая кинетика за фронтом сильных ударных волн, радиационно-столкновительные модели, экспериментальные данные по неравновесному излучению, модели возбуждения электронных состояний двух-атомных молекул при столкновении с электронами.
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