Валидация моделей поуровневой колебатель-но-химической кинетики на примере задачи о релаксации воздуха в послеразрядной зоне


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Validation of state-to-state models of vibrational-chemical kinetics in the problem of air relaxation in the afterglow

Air relaxation in the afterglow of a DC pulse discharge was simulated using the state-to-state approach and two kinetic schemes. Good agreement of the results with experiment is shown. Key factors affecting the accuracy of the simulation were identified: consider-ation of vibrational nonequilibrium in all molecular species, the exchange Zeldovich reaction model, and the model for vibrational energy exchanges. A reduced kinetic scheme was developed that speeds-up calculations by 37 times saving the accuracy. The proposed model is applicable in a wide range of temperatures and nonequilibrium parameters.

pulsed DC discharge, state-to-state vibrational chemical kinetics, exchange reactions, vibrational excitation, electronic excitation

DOI: http://doi.org/10.33257/PhChGD.26.2.1185


Том 26, выпуск 2, 2025 год



Проведено поуровневое моделирование релаксации воздуха в послеразрядной зоне импульсного разряда постоянного тока с использованием двух кинетических схем. Показано хорошее согласие результатов расчета с экспериментом. Выявлены ключевые факторы, влияющие на точность моделирования: учёт колебательной неравновесности всех молекулярных компонентов, модель обменных реакций Зельдовича и модель обменов колебательной энергией. Разработана сокращённая кинетическая схема, ускоряющая расчёты в 37 раз при сохранении точности. Предложенная модель применима в широком диапазоне температур и параметров неравновесности.

импульсный разряд постоянного тока, поуровневая колебательно–химическая кинетика, обменные реакции, колебательное возбуждение, электронное возбуждение

DOI: http://doi.org/10.33257/PhChGD.26.2.1185


Том 26, выпуск 2, 2025 год



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